As the size of components get smaller, it becomes impossible to label them intelligibly, or even to label them at all.
Some manufacturers do provide laser markings on their chip capacitors to prevent surface degradation or induced micro-cracks; these codes are based on the EIA RS 198 standards which use 2- or 3-digit alphanumeric codes to represent capacitance values. With these codes, you can then look up their product datasheet reference to determine the values. For example, A5 = 100,000pF or 100nF, where N denotes the vendor NovaCap.
But what do you do with SMD components without markings?
While you're more likely to encounter chip capacitors with no markings than chip resistors, resolving the latter is a much simpler and straightforward affair. A normal digital multimeter can usually measure resistors in-circuit quite accurately without interference from adjacent components, unless there are parallel resistors or low impedance path across the resistor in question.
Unfortunately there's no way you can measure a capacitor in-circuit due to PCB track capacitances as well as induced lead and bond-wire capacitances of components around it. For the most part, you can get some hint from the usage of these SMD capacitors. You can find out more on this and other topics in the book The Art of PCB Reverse Engineering.
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